1H (700 MHz) and 13C (150 MHz) NMR data of 1 in CD3OD:CDCl3 = 1:1.
Position | 1 | Position | 1 | ||
---|---|---|---|---|---|
1 | 172.4, C |
1' | 172.4, C |
||
2 | 2' | ||||
3 | 78.7, CH | 4.86, m | 3' | 78.7, CH | 4.86, m |
4 | 33.4, CH2 | 3.19, m 3.06, m |
4' | 33.4, CH2 | 3.19, m 3.06, m |
4a | 133.8, C | 4a' | 133.8, C | ||
5 | 117.3, CH | 7.05, s | 5' | 117.3, CH | 7.05, s |
5a | 141.0, C | 5a' | 141.0, C | ||
6 | 99.0, CH | 6.76, s | 6' | 99.0, CH | 6.76, s |
7 | 162.6, C | 7' | 162.6, C | ||
8 | 109.0, C | 8' | 109.0, C | ||
9 | 155.8, C | 9' | 155.8, C | ||
9a | 109.0, C | 9a' | 109.0, C | ||
10 | 163.8, C | 10' | 163.8, C | ||
10a | 100.2, C | 10a' | 100.2, C | ||
11 | 56.4, CH3 | 3.82, s | 11' | 56.4, CH3 | 3.82, s |
12 | 42.7, CH2 | 2.10, m 1.92, m |
12' | 42.7, CH2 | 2.10, m 1.92, m |
13 | 68.6, CH | 4.10, m |
13' | 67.8, CH | 4.10, m |
14 | 44.8, CH2 | 1.61, m |
14' | 43.7, CH2 | 1.66, m 1.59, m |
15 | 72.1, CH | 3.80, m | 15' | 70.8, CH | 4.05, m |
16 | 38.6, CH2 | 1.44, m |
16' | 44.2, CH2 | 1.67, m 1.59, m |
17 | 26.0, CH2 | 1.42, m 1.30, m |
17' | 71.3, CH | 4.03, m |
18 | 30.3, CH2 | 1.24, m |
18' | 44.3, CH2 | 1.59, m 1.52, m |
19 | 30.3, CH2 | 1.24, m |
19' | 71.6, CH | 3.77, m |
20 | 32.5, CH2 | 1.25, m | 20' | 40.7, CH2 | 1.42, m |
21 | 23.3, CH2 | 1.27, m | 21' | 19.2, CH2 | 1.41, m 1.34, m |
22 | 14.4, CH3 | 0.86, dd (8.5, 5.3) | 22' | 14.4, CH3 | 0.90, dd (8.5, 5.3) |